Bubbles in Microchannels
Thomas Cubaud and Chih-Ming Ho
Work supported by DARPA/MTO Micro Power Generation Program






Multiphase flow occurs in many operations in the chemical, petroleum, and power generation industries (such as nuclear power plants and micro fuel cells). Unlike large-scale systems, gas bubbles can present significant problems in microfluidic systems by disturbing and eventually blocking the flow.
Understanding how bubbles affect the flow resistance in microchannels is, beside its fundamental aspect, a concern of determining the pumping or energy requirement for portable microfluidic devices where two-phase flow is involved such as in a micro direct methanol fuel cell (
μDMFC).
Bubbly flow in 525-um channel

Flow patterns in 525 μm square channel (play movie ~ 7 Mb)




Channels are made with glass and silicon using microfabrication techniques. Channel masks are printed in positive with a high-resolution printer on transparent paper for lithography. Photoresist is spin coated on a silicon wafer. The wafer is then exposed to UV light through the mask. Channels are etched at different depths using Deep Reactive Ion Etching (DRIE). The sealing is made with Pyrex glass using anodic bonding, providing optical access for flow analysis.




Two-phase flow microchannel module

Two-phase flow microchannel module

mixing section

On-chip cross-shaped mixing section



Properly introducing gas bubbles is an important step in producing a two-phase flow pattern. We micromachined an effective small mixing section on-chip. Well-defined bubbles in a wide range of sizes can be produced as a function of liquid and gas flow rates. Because of the square channel symmetries, bubbles flow “naturally” in the center of the channel. The cross-shaped was chosen to produce a steady uniform flow. The minimal size of bubbles is about the size of the channel. In these experiments, this mixing system is used as an effective way to produce two-phase flows in microdevices.


Flow patterns

Two-phase flows are distributed into several distinct flow patterns depending on the liquid and gas flow rates (respectively QL and QG) and fluid and channel properties. Five main flow regimes were observed in the partially wetting square microchannels: bubbly, wedging, slug, annular, and dry flows. Transitions between regimes are predictable as a function of liquid and gas flow rates. For 200 and 525 μm channels, transitions between each regime occur for fixed values of the homogeneous liquid fraction αL defined as αL = QL / (QL + QG).

bubbly flow
Bubbly flow (play movie ~ 5 Mb)

wedging
Wedging flow (play movie ~ 5 Mb)

flow map
Air/water flow map

slug flow
Slug flow



annular flow
Annular flow
dry flow
Dry flow

Pressure drop and resistance to flow

Pressure drop caused by frictional force in two-phase flow is a parameter of prime interest to determine the conditions for the flow.
pressure

Two-phase flow pressure drop


The two-phase pressure drop ΔP2-phase was scaled by the single liquid flow pressure drop ΔPL associated to the liquid flow rate QL in the channel (ΔPL = RLQL). As can be seen in the figure, data collapse more or less on a single master curve with two distinct regimes. The bubbly and the wedging flows are depicted on one side and the slug, annular and dry flows are on the other side.
resistance

Two-phase flow resistance


As αL changes from 1 to 0, the system goes from a single liquid flow to a single gas flow. The fluidic resistance R = ΔP/Q is an interesting parameter because it is calculable from direct measurements without assuming any correlation.


Surface modifications

We study the shape of static and moving bubbles in microchannels with square cross-sections for different contact angles. When liquid and gas are flowing in microchannels, dynamic contact angles play an important role in the selection of the flow regime. This figure describes liquid/gas flow patterns obtained with an on-chip liquid/gas mixer in square microchannels with surface modifications (hydrophobic/ hydrophilic). Pure water and air, as well as aqueous foam flow patterns were investigated and showed a rich variety of regimes.

surface modifications


For more information, consult the related articles or contact the authors.
Ho's laboratory 2004